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ASME BPVC 2023 Section II part D (metric)

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NONMANDATORY APPENDIX A
ISSUES ASSOCIATED WITH MATERIALS USED IN ASME CODE
CONSTRUCTION
A-100 GENERAL
The performance over time of the various ferrous and
nonferrous alloys permitted for use in Code construction
may be influenced by many factors, ranging from the processes
involved in their fabrication into components and
their installation to changes in the material structure or
direct damage to the material related to operation in
the intended service. If Code-constructed equipment is
to provide the reasonably long period of safe operation
expected by the users of that equipment, then the equipment
designers must be aware of any potential change in
the materials properties related to fabrication, installation,
or service as they go about selecting materials for
Code usage. Although the Code does not mandate that
all of the various metallurgical phenomena and environmental
effects that can influence material performance
be considered in the design of a Code component, such
consideration is a part of the good engineering judgment
that is expected to be exercised in all Code-related matters
and, as such, this Nonmandatory Appendix is provided
to designers and other Code users to assist in the
material selection process.
Historically, some of the information contained in this
Nonmandatory Appendix has been available in other Sections
of the Boiler and Pressure Vessel Code, as well as in
the Piping Code. In addition to information provided previously
in Nonmandatory Appendix A, Metallurgical Phenomena,
in Section II, Part D, there was information
available in Section VIII and more recently in Section III
Appendices, Nonmandatory Appendix W, Environmental
Effects. A review of these various information sources revealed
that there were many important issues not covered,
and that there were other issues that required
revision to incorporate new information. Thus, what follows
is an expanded coverage of metallurgical phenomena
and environmental effects. It is emphasized,
however, that this is not a comprehensive coverage of
all possible mechanisms, nor is it an exhaustive treatment
of the individual topics. Rather, this revised Appendix is
intended to serve as a more convenient resource for designers
and users of Code equipment as they consider
the many issues that could adversely affect materials in
Code service.
A-110 ISSUES COVERED
Issues covered in this Nonmandatory Appendix include
those listed below it is recognized, of course, that some
of these issues could be placed in more than one of the

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general categories. In the first section, on metallurgical
changes A-200, an attempt is made to identify the materials
most commonly affected by the changes in question.
In the remaining sections A-300 through A-800, the various
types of damage to which materials may be subject
are described, with a strong emphasis on the environmental
effects that, in the absence of appropriate preventive
measures, can render the materials inoperable. Items
covered in each section and paragraph are as follows:
Section/
Paragraph
Number Section/Paragraph Description
A-200 Metallurgical changes
A-201 Graphitization occurs almost exclusively in carbon and
CMo steels
A-202 Softening occurs in most ferritic alloys used for elevated
temperature service
A-203 Temper embrittlement occurs in low alloy steels
A-204 Strain aging occurs in carbon and low alloy steels
A-205 Cold working effects occur in most steels, but are
particularly important for the 300 series stainless
steels
A-206 Relaxation cracking
A-207 475°C embrittlement occurs mostly in high chromium
stainless steels and in the ferritic phase of duplex
stainless steels
A-208 Sigma phase embrittlement occurs in 300 series
stainless steels and in some 400 series stainless steels
with Cr >17
A-209 Laves phase precipitation occurs in some 300 series
stainless steels, FeNi base alloys, Co-base superalloys,
and in the tungsten-bearing CSEF steels
A-210 Sensitization carbide formation occurs in both the 300
series stainless steels as well as in 400 series stainless
grades
A-211 Thermal aging embrittlement occurs to varying degrees
in most ferrous alloys
A-212 Radiation embrittlement affects all materials, both
ferrous and nonferrous
A-213 Solidification cracking in nickel alloys
A-300 Uniform corrosion
A-301 General corrosion and wastage
A-302 Atmospheric corrosion
A-303 Galvanic corrosion
A-304 Stray current corrosion
ASME BPVC.II.D.M-2023
1315